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CO2气氛下生物质焦气化反应动力学模型研究:Ⅱ.指数前因子

汪小憨 宋谦石 曾小军 吴勇

燃料化学学报2017,Vol.45Issue(5):529-536,8.
燃料化学学报2017,Vol.45Issue(5):529-536,8.

CO2气氛下生物质焦气化反应动力学模型研究:Ⅱ.指数前因子

Modeling study on the biomass char gasification kinetics under CO2 atmosphere: II.Pre-exponential factor

汪小憨 1宋谦石 2曾小军 1吴勇3

作者信息

  • 1. 中国科学院广州能源研究所, 广东 广州 510640
  • 2. 中国科学院可再生能源重点实验室, 广东 广州 510640
  • 3. 中国科学院大学, 北京 100049
  • 折叠

摘要

Abstract

Based on the simple collision theory (SCT),the calculation method of biomass char gasification rate was developed and the combined parameters to characterize the pre-exponential factor were found.Furthermore,some experimental tests for six acid-washed biomass chars,such as the isothermal gasification and so on,were performed under CO2 atmosphere,using a thermo-gravimetric analyzer (TGA) over the temperature ranges of 800-1000℃,respectively.Through the comparison of experimental data and modeling results,it is found that a good agreement is made and the developed model equations can provide an effective guidance to clarify the general gasification law of biomass chars.

关键词

生物质焦炭/CO2气化/简单碰撞理论/指数前因子/模型研究

Key words

biomass char/CO2 gasification/simple collision theory/pre-exponential factor/modelling

分类

能源科技

引用本文复制引用

汪小憨,宋谦石,曾小军,吴勇..CO2气氛下生物质焦气化反应动力学模型研究:Ⅱ.指数前因子[J].燃料化学学报,2017,45(5):529-536,8.

基金项目

The project was supported by the National Natural Science Foundation of China (51276184).国家自然科学基金(51276184)资助 (51276184)

燃料化学学报

OA北大核心CSCDCSTPCD

2097-213X

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