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硫化镍/三维网络石墨烯复合材料制备及其在高性能超级电容器的应用研究

王晓敏 窦湟琳 田真 张久俊

电化学2017,Vol.23Issue(2):217-225,9.
电化学2017,Vol.23Issue(2):217-225,9.DOI:10.13208/j.electrochem.161246

硫化镍/三维网络石墨烯复合材料制备及其在高性能超级电容器的应用研究

Novel Composites between Nano-Structured Nickel Sulfides and Three-Dimensional Graphene for High Performance Supercapacitors

王晓敏 1窦湟琳 1田真 1张久俊2

作者信息

  • 1. 太原理工大学材料科学与工程学院,山西太原
  • 2. 上海大学理学院/可持续能源研究院,上海
  • 折叠

摘要

Abstract

In this paper,a three-dimensional graphene (3DG) network grown on nickel foam was employed as a template for synthesizing graphene-based composite materials of supercapacitor electrode.The composites (crystal Ni3S2 nanorods on the surface of 3DG (abbreviated as Ni3S2/3DG)) were obtained through a one-step hydrothermal reaction.The morphological and structural evolution of the Ni3S2/3DG composites were investigated by SEM,TEM,XRD and Raman spectroscopy.Detailed electrochemical characterization showed that the Ni3S2/3DG-coated electrodes exhibited both a specific capacitance as high as 1825 F·g-1 at 5 mV·s-1 and a discharge capacitance as high as 517 F· g-1 at 10 mA.Remarkably,a high cycling performance (~ 100% capacitance retention after 1000 cycles) is achieved at a current density of 20 mA.

关键词

三维石墨烯/硫化镍/超级电容器/电化学储能

Key words

three-dimensional graphene/nickel sulfide/supercapacitor/electrochenical energy storage

分类

化学化工

引用本文复制引用

王晓敏,窦湟琳,田真,张久俊..硫化镍/三维网络石墨烯复合材料制备及其在高性能超级电容器的应用研究[J].电化学,2017,23(2):217-225,9.

基金项目

This work was supported by the National Natural Science Foundation of China (Grant No.51372160 and 51172152). (Grant No.51372160 and 51172152)

电化学

OA北大核心CSCDCSTPCD

1006-3471

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