生物加工过程2017，Vol.15Issue(3)：53-58,6.DOI:10.3969/j.issn.1672-3678.2017.03.009
离子液体介导玉米秸秆制备5-羟甲基糠醛
Preparation of 5-hydroxymethylfurfural from corn stover mediatedby ionic liquids
摘要
Abstract
We prepared 5-hydroxymethylfurfural (5-HMF) from corn stover in a mixed solvent of ionic liquid 1-butyl-3-methylimidazolium chloride ([BMIM]Cl) and dimethyl sulfoxide (DMSO) with CrCl3·6H2O and sulfuric acid as catalyst.We optimized reaction conditions,including reaction time,temperature,amount of catalysts,the ratio of solid to liquid and the mass ratio of [BMIM]Cl) to DMSO.Products were determined by high performance liquid chromatography.Yield of 5-HMF reached 53.3% when acidolysis of corn stover was at 150 ℃,with solid-liquid ratio of 3.8%,m([BMIM]Cl)/m(DMSO)=1,H2SO4 loading of 6.7% and CrCl3·6H2O loading of 13.3%,and reaction time of 80 min.关键词
离子液体/玉米秸秆/5-羟甲基糠醛Key words
ionic liquids/corn stover/5-hydroxymethylfurfural分类
化学化工引用本文复制引用
王领民,张全,刘斯雨,关浩,高慧鹏..离子液体介导玉米秸秆制备5-羟甲基糠醛[J].生物加工过程,2017,15(3):53-58,6.基金项目
中国石油化工股份有限公司委托开发项目(414057) （414057）
