应用化学2017，Vol.34Issue(5)：489-501,13.DOI:10.11944/j.issn.1000-0518.2017.05.160477
氢氧根和烷氧基负离子含氧亲核试剂在富勒烯衍生化中的应用
Application of Oxygen Nucleophiles Hydroxyl and Alkoxide Anions in Derivatization of Fullerenes
摘要
Abstract
Due to the promising potentials shown by fullerene derivatives for applications in the areas of organic photovoltaics, biology and medicine, derivatization of fullerenes has attracted great interest and a range of methods are well developed.It is typical for fullerenes to undergo reactions with nucleophiles due to their strong electron-deficiency.However, compared to carbon nucleophiles, reactions of oxygen nucleophiles with fullerenes have received less attentions.Herein, combined with our previous work, the use of hydroxyl anion(OH-) and alkoxide anion(MeO-) in the derivatization of fullerenes is reviewed, and the related reaction mechanisms are discussed, which may shed light on exploring new methods for fullerene derivatization.关键词
富勒烯/含氧亲核试剂/杂环化合物/反应机理/空间选择性Key words
fullerenes/oxygen nucleophiles/heterocyclic compounds/reaction mechanism/regioselectivity分类
化学化工引用本文复制引用
赫法贵,高翔..氢氧根和烷氧基负离子含氧亲核试剂在富勒烯衍生化中的应用[J].应用化学,2017,34(5):489-501,13.基金项目
国家自然科学基金(21472183)、吉林省科技发展计划项目(20170101172JC)资助 （21472183）
Supported by the National Natural Science Foundation of China(No.21472183), Jilin Provincial Science and Technology Department(No.20170101172JC) （No.21472183）
