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废油脂制备表面活性剂及在浮选脱墨中的应用

唐振 胡硕 孙广卫 韩颖 周景辉

中国造纸2017,Vol.36Issue(5):25-29,5.
中国造纸2017,Vol.36Issue(5):25-29,5.DOI:10.11980/j.issn.0254-508X.2017.05.005

废油脂制备表面活性剂及在浮选脱墨中的应用

Preparation of Surfactants from Waste Oil and Application in Flotation Deinking

唐振 1胡硕 1孙广卫 1韩颖 1周景辉1

作者信息

  • 1. 大连工业大学轻工与化学工程学院,辽宁大连,116034
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摘要

Abstract

Two kinds of surfactants fatty amide propyl dimethyl amine and fatty amide type quaternary ammonium salt could be synthesized bywaste edible vegetable oil (Abbreviation:waste oil).The optimal conditions of synthesizing fatty amido propyl dimethyl amine were obtainedby conditional experiments with temperature of 110℃,time of 2 h,material ratio of 1 ∶ 1.1,conversion rate of 62%;the optimal conditions of synthesizing fatty acid type quaternary ammonium salt using isopropyl alcohol as solvent were determined as the follows:temperature 72℃,time 0.5 h,solvent content 20%,conversion rate 82.7%.This paper verified the deinking effenciencies of these two surfactants for old newspaper,and compared their deinking results with AEO-9 and commercial soap.Results showed that the deinked pulp brightness using these two surfactants separately was superior to AEO-9 and commercial soap,the brightness of the pulp deinked with the mixture of these two surfactants in the ratio of 1:1 could reached to 54.3%,these two surfactants mixed with AEO-9 separately could achieve 6 and 6 percentage points higher brightness than using AEO-9 alone.

关键词

废弃食用油/表面活性剂/酰胺类表面活性剂/季铵盐表面活性剂

Key words

waste oil/deinking agent/amide surfactants/quaternary ammonium salt surfactants

分类

轻工纺织

引用本文复制引用

唐振,胡硕,孙广卫,韩颖,周景辉..废油脂制备表面活性剂及在浮选脱墨中的应用[J].中国造纸,2017,36(5):25-29,5.

基金项目

辽宁省科技厅,基于纤维素纳米晶体模板的二氧化钛纳孔薄膜材料的制备(201602054). (201602054)

中国造纸

OA北大核心

0254-508X

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