中国造纸2017,Vol.36Issue(5):25-29,5.DOI:10.11980/j.issn.0254-508X.2017.05.005
废油脂制备表面活性剂及在浮选脱墨中的应用
Preparation of Surfactants from Waste Oil and Application in Flotation Deinking
摘要
Abstract
Two kinds of surfactants fatty amide propyl dimethyl amine and fatty amide type quaternary ammonium salt could be synthesized bywaste edible vegetable oil (Abbreviation:waste oil).The optimal conditions of synthesizing fatty amido propyl dimethyl amine were obtainedby conditional experiments with temperature of 110℃,time of 2 h,material ratio of 1 ∶ 1.1,conversion rate of 62%;the optimal conditions of synthesizing fatty acid type quaternary ammonium salt using isopropyl alcohol as solvent were determined as the follows:temperature 72℃,time 0.5 h,solvent content 20%,conversion rate 82.7%.This paper verified the deinking effenciencies of these two surfactants for old newspaper,and compared their deinking results with AEO-9 and commercial soap.Results showed that the deinked pulp brightness using these two surfactants separately was superior to AEO-9 and commercial soap,the brightness of the pulp deinked with the mixture of these two surfactants in the ratio of 1:1 could reached to 54.3%,these two surfactants mixed with AEO-9 separately could achieve 6 and 6 percentage points higher brightness than using AEO-9 alone.关键词
废弃食用油/表面活性剂/酰胺类表面活性剂/季铵盐表面活性剂Key words
waste oil/deinking agent/amide surfactants/quaternary ammonium salt surfactants分类
轻工纺织引用本文复制引用
唐振,胡硕,孙广卫,韩颖,周景辉..废油脂制备表面活性剂及在浮选脱墨中的应用[J].中国造纸,2017,36(5):25-29,5.基金项目
辽宁省科技厅,基于纤维素纳米晶体模板的二氧化钛纳孔薄膜材料的制备(201602054). (201602054)