化工学报2017,Vol.68Issue(6):2394-2398,5.DOI:10.11949/j.issn.0438-1157.20161755
二芳基二硫醚与硝基芳烃的反应
Reaction of diaryl disulfides with nitroarenes
摘要
Abstract
The cheap and readily available Rongalite?/K2CO3 promoted the reaction of diaryl disulfides with nitroarenes in DMSO at 50℃, providing a convenient route to the synthesis of unsymmetrica diaryl sulfide. The structures of all products were characterized by1H NMR and13C NMR. This protocol had some distinct advantages of mild conditions, readily available starting materials and simple work-up.关键词
二芳基二硫醚/硝基芳烃/甲醛次硫酸氢钠/二芳基硫醚/反应机理Key words
diaryl sulfide/nitroarenes/sodium formaldehyde sulfoxylate/diaryl sulfide/reaction mechanism分类
化学化工引用本文复制引用
李术艳,孙莉娜,沈淑君,程天行,程双华,陈久喜..二芳基二硫醚与硝基芳烃的反应[J].化工学报,2017,68(6):2394-2398,5.基金项目
浙江省自然科学基金项目(LY16B020012) (LY16B020012)
福建省教育厅科技计划项目(JA13388).supported by the Natural Science Foundation of Zhejiang Province(LY16B020012) and the Educational Foundation of Fujian Province(JA13388). (JA13388)