生物质化学工程2017，Vol.51Issue(3)：21-26,6.DOI:10.3969/j.issn.1673-5854.2017.03.004
橡胶籽油基多元醇的制备与表征
Preparation and Characterization of Rubber Seed Oil Based Polyol
摘要
Abstract
Rubber seed oil based polyol was prepared by using epoxidized rubber seed oil(ERSO) as raw materials,methanol and isopropanol as ring-opening reagents,and fluoboric acid as catalyst,the preparation conditions were investigated with the hydroxyl value of product as index,and the characterization of product was also studied.The results showed that the optimum reaction conditions were reaction time 30min,reaction temperature 70℃,the mass ratio of to alcohol to ERSO 4∶1,the amount of fluoboric acid 1%(based on the mass of ERSO),the mass ratio of isopropanol to methanol 1∶1.The results of verification experiment showed that the acid value,hydroxyl value,average molecular weight,moisture content and viscosity of rubber seed oil based polyol prepared under the optimum reaction conditions were 2.68mg/g,219.32mg/g,870.21,0.08% and 4791mPa·s,respectively.Furthermore,the chemical structure of rubber seed oil based polyol was characterized by FT-IR,1H NMR and 13C NMR,the results showed that the polyol was formed by the ring-opening reaction of epoxy group of ERSO.关键词
橡胶籽油基多元醇/环氧-羟基化法/环氧橡胶籽油Key words
rubber seed oil based polyol/epoxidation-hydroxylation method/epoxidized rubber seed oil分类
化学化工引用本文复制引用
黄元波,郑志锋,马焕,郑云武,刘灿,龚慧颖,杨晓琴..橡胶籽油基多元醇的制备与表征[J].生物质化学工程,2017,51(3):21-26,6.基金项目
云南省教育厅重点项目资助项目(2014Z110) （2014Z110）
国家自然科学基金(31200452) （31200452）
云南省应用基础研究青年项目(2014FD029) （2014FD029）
