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碱木质素填充天然橡胶的特性研究

张翠美 崔雪静 孙艳妮 姜瑞玉 赵季若 冯莺

生物质化学工程2017,Vol.51Issue(3):33-40,8.
生物质化学工程2017,Vol.51Issue(3):33-40,8.DOI:10.3969/j.issn.1673-5854.2017.03.006

碱木质素填充天然橡胶的特性研究

Characteristic of Alkali Lignin Filling Natural Rubber

张翠美 1崔雪静 2孙艳妮 3姜瑞玉 1赵季若 2冯莺3

作者信息

  • 1. 青岛科技大学山东省烯烃催化与聚合重点实验室
  • 2. 橡塑材料与工程教育部重点实验室
  • 3. 山东省橡塑材料与工程重点实验室,山东 青岛 266042
  • 折叠

摘要

Abstract

The performance of alkali lignin filling natural rubber was studied.The characteristic of network structure of filler in rubber compound and its influence on dynamic mechanical properties were investigated.The vulcanizate was observed and analyzed by scanning electron microscopy(SEM),mechanical properties and dynamic mechanical properties test.The results showed that there was almost no filler-filler interactions in alkali lignin filled vulcanizate,the rubber-filler interactions was very weak,and the alkali lignin particles agglomerated when the filling amounts of alkali lignin were 10%-50%.The mechanical properties of vulcanizate were not decreased largely after filling alkali lignin.The tensile strength of 10% alkali lignin filled vulcanizate was 30MPa,higher than that of no alkali lignin filled sample(28.7MPa).The filling of alkali lignin partly accelerated the vulcanization of rubber.The crosslinking density was increased with the addition of alkali lignin and it decreased when the filling amount of alkali lignin was 50%,with the tensile strength of 20.1MPa.The aging resistance was improved with the increase of the amount of alkali lignin.And there was no obvious impact on the vulcanizate′s wet skid resistance and rolling resistance with the filling of alkali lignin.

关键词

碱木质素/天然橡胶/Payne效应/力学性能

Key words

alkali lignin/natural rubber/Payne effect/mechanical properties

分类

化学化工

引用本文复制引用

张翠美,崔雪静,孙艳妮,姜瑞玉,赵季若,冯莺..碱木质素填充天然橡胶的特性研究[J].生物质化学工程,2017,51(3):33-40,8.

生物质化学工程

OA北大核心

1673-5854

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