生物质化学工程2017，Vol.51Issue(3)：55-64,10.DOI:10.3969/j.issn.1673-5854.2017.03.009
生物油含氧化合物加氢脱氧反应机理研究进展
Hydrodeoxygenation Mechanism of Oxygenated Compounds in Bio-oils
摘要
Abstract
The differences in the composition of the oxygenated compounds in bio-oil prepared by different biomass were presented.Then the reaction mechanisms of hydrodeoxygenation(HDO) of the main oxygenated compounds(phenols,furans,ethers,acids and esters) were reviewed,and the HDO kinetic data and reaction pathways were described in detail.Meanwhile,the HDO reaction processes of real bio-oil feeds were sketched,and the removal activities of heteroatoms O,N,S catalyzed by different catalysts were also discussed.Moreover,the problem of the hydrotreating of bio-oil was pointed out that we know little about the reaction mechanism of real bio-oil,and the HDO of model compounds can not reflect the reaction process of real bio-oil,thus the interaction of different types of oxygenated compounds and the reaction mechanism of real bio-oil should emphasically be studied.关键词
生物油/含氧化合物/加氢脱氧/反应动力学/反应路径Key words
bio-oils/oxygenated compound/hydrodeoxygenation/reaction kinetics/reaction pathway分类
化学化工引用本文复制引用
徐冬梅,纪道玉,孟凡禹,张华倩,聂小雷,刘迪..生物油含氧化合物加氢脱氧反应机理研究进展[J].生物质化学工程,2017,51(3):55-64,10.基金项目
国家自然科学基金资助项目(21306106) （21306106）
