天然产物研究与开发2017,Vol.29Issue(4):601-604,583,5.DOI:10.16333/j.1001-6880.2017.4.012
Au/C催化剂的制备及其对木质素模型化合物的催化氧化研究
Preparation and Catalytic Oxidation Performance of Au/C Catalyst for Lignin Model Compound
摘要
Abstract
The activated carbon-supported Au catalyst was prepared by the impregnation method using acid-treated activated carbon as the support.The effects of this catalyst in the catalytic oxidative degradation of lignin model compound 2-(2-methoxyphenoxy)-1-phenyl ethanol were investigated.The results revealed that lignin model compound underwent catalytic oxidation to produce guaiacol as the primary product and its conversion yield could reach up to 88% at 150 ℃ and 1.0 Mpa using methanol as solvent,oxygen as oxidant.A possible mechanism producing guaiacol was presented.关键词
Au/C催化剂/木质素模型化合物/催化氧化Key words
Au/C catalyst/lignin model compound/catalytic oxidation分类
化学化工引用本文复制引用
耿莉莉,何伟,魏婷,周婷婷,周瑞,张宏喜..Au/C催化剂的制备及其对木质素模型化合物的催化氧化研究[J].天然产物研究与开发,2017,29(4):601-604,583,5.基金项目
国家自然科学基金(21663002) (21663002)
新疆维吾尔自治区高校科研计划(XJEDU2016S083) (XJEDU2016S083)
昌吉学院科研基金(2014YJYB007) (2014YJYB007)