物理化学学报2017，Vol.33Issue(6)：1085-1107,23.DOI:10.3866/PKU.WHXB201704114
LiFePO4电化学反应机理、制备及改性研究新进展
New Research Progress of the Electrochemical Reaction Mechanism,Preparation and Modification for LiFePO4
摘要
Abstract
Lithium-ion batteries have been extensively studied due to their excellent electrochemical performance as an effective energy storage device for sustainable energy sources.The key to the development and application of this technology is the improvement of electrode materials.LiFePO4 has captured the attention of researchers both home and abroad as a potential cathode material for lithium-ion batteries because of its long cycle life,energy density,stable charge/discharge performance,good thermal stability,high safety,light weight and low toxicity.However,there are still some technical bottlenecks in the application of LiFePO4,such as relatively low conductivity,low diffusion coefficient of lithium ions,and low tap density.Moreover,the cycle performance,low-temperature characteristics,and rate performance are not ideal,restricting its application and development.In recent years,researchers have sought to solve these problems by improving the preparation process and attempting related modifications.In this paper,we have provided a systemic review of the structure,electrochemical reaction mechanism,preparation,and modification of LiFePO4.The main problems associated with LiFePO4 cathode materials and possible solutions are discussed.We have also investigated the future research direction and application prospect of LiFePO4 cathode materials.关键词
LiFePO4/研究进展/电化学反应机理/制备方法/改性Key words
LiFePO4/Research progress/Electrochemical reaction mechanism/Preparation method/Modification分类
化学化工引用本文复制引用
张英杰,朱子翼,董鹏,邱振平,梁慧新,李雪..LiFePO4电化学反应机理、制备及改性研究新进展[J].物理化学学报,2017,33(6):1085-1107,23.基金项目
The project was supposed by the National Natural Science Foundation of China (51604132).国家自然科学基金(51604132)资助项目 （51604132）
