物理化学学报2017，Vol.33Issue(6)：1108-1113,6.DOI:10.3866/PKU.WHXB201703222
金属粉末的吸氢统计热力学模型
Statistic Thermodynamic Model of Hydrogen Absorption on Metal Powders
摘要
Abstract
Based on zero-order Bragg-Williams approximation,a new statistic thermodynamic model is presented herein.The distinctive feature of the new model is that an apparent compressibility factor α is introduced to correct the volume change of high-pressure gases and ensure no loop-like curves are obtained in the fitting results.The new model is successfully applied to investigate hydrogen absorption on metal powders.Our results indicate that the model works very well and can be used to predict PCT curves at different temperatures.Hence,our new model exhibits significant potential for application in practical systems.关键词
统计热力学理论/氢化过程/储氢材料粉末Key words
Statistic thermodynamic theory/Hydriding process/Hydrogen storage materials powder分类
化学化工引用本文复制引用
吴广新,彭望君,张捷宇..金属粉末的吸氢统计热力学模型[J].物理化学学报,2017,33(6):1108-1113,6.基金项目
The project was supported by the National Natural Science Foundation of China (51104098,51674163) and Science and Technology Committee of Shanghai,China (14521100603,16ZR1412000).国家自然科学基金(51104098,51674163)和上海科学技术委员会(14521100603,16ZR1412000)资助 （51104098,51674163）
