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合成条件对钙矾石形貌的影响

张文生 张金山 叶家元 王宏霞 张建波 刘锦成

硅酸盐学报2017,Vol.45Issue(5):631-638,8.
硅酸盐学报2017,Vol.45Issue(5):631-638,8.DOI:10.14062/j.issn.0454-5648.2017.05.05

合成条件对钙矾石形貌的影响

Influence of Synthesis Conditions on Morphology of Ettringite

张文生 1张金山 1叶家元 1王宏霞 1张建波 1刘锦成1

作者信息

  • 1. 中国建筑材料科学研究总院,绿色建筑材料国家重点实验室,北京100024
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摘要

Abstract

Ettringite is a main product of sulphur aluminate cement hydration,and it has a more significant influence on the performance of cement and concrete.The formation conditions of ettringite affects its morphology.In this work,ettringite was synthesized by a chemical method.The influence of synthesis conditions on the formation and morphology of ettringite was investigated.The results show that the morphology of ettringite and the length-width ratio are significantly different due to the use of different synthetic materials.The formation of ettringite can be promoted at elevated temperature.Ettringite can be formed at 80 ℃ and shows lots of morphologies.Ettringite is unstable at 100 ℃.The length-width ratio of ettringite decreases with the increase of solution pH value.Boric acid inhibits the growth of ettringite in the (001) direction.

关键词

钙矾石/合成条件/形貌/形成过程

Key words

ettringite/synthesis conditions/morphology/formation process

分类

化学化工

引用本文复制引用

张文生,张金山,叶家元,王宏霞,张建波,刘锦成..合成条件对钙矾石形貌的影响[J].硅酸盐学报,2017,45(5):631-638,8.

基金项目

国家自然科学基金(51102222)和国家重点研发计划(2016YFB0303504)资助. (51102222)

硅酸盐学报

OA北大核心CSCDCSTPCD

0454-5648

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