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高固含发泡酚醛树脂的制备过程分析及应用研究

胡琳 杨苏 郑欣欣 曹苏生 马玉峰

合成材料老化与应用2017,Vol.46Issue(2):7-12,6.
合成材料老化与应用2017,Vol.46Issue(2):7-12,6.

高固含发泡酚醛树脂的制备过程分析及应用研究

Preparation Process Analysis and Application Research of High Solid Content and Foamable Phenolic Resin

胡琳 1杨苏 1郑欣欣 1曹苏生 1马玉峰1

作者信息

  • 1. 南京林业大学材料科学与工程学院,江苏南京210037
  • 折叠

摘要

Abstract

Paraformaldehyde was chose to replace forrnaldehyde solution as raw material in the synthesis of high solid content and foamable resole phenolic resin.The effects of reaction time on the properties of phenolic resin were investigated.The results showed that the viscosity and solid content of phenolic resin was increased gradually,the content of free phenol and free formaldehyde were reduced gradually,heat resistance was slightly reduced with the increase of reaction time.At the end of the reaction,the viscosity,solid content,free phenol,free formaldehyde and carbon residue (900℃) were respectively 8000mPa· s,77.01%,1.42%,0.53% and 60.14%.The viscosity,solid content meet the requirements of foaming resin,and the free phenol and formaldehyde content was low,heat resistance was high,bubble hole were smaller and distributed more uniformly.

关键词

酚醛树脂/固体含量/结构分析/热分析/酚醛泡沫

Key words

phenolic resin/solid content/structure analysis/thermoanalysis/phenolic foam

分类

化学化工

引用本文复制引用

胡琳,杨苏,郑欣欣,曹苏生,马玉峰..高固含发泡酚醛树脂的制备过程分析及应用研究[J].合成材料老化与应用,2017,46(2):7-12,6.

基金项目

江苏省自然科学基金项目(青年基金)(BK20140978) (青年基金)

南京林业大学大学生实践创新训练计划项目(2015sjcx057) (2015sjcx057)

合成材料老化与应用

OACSTPCD

1671-5381

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