杭州师范大学学报(自然科学版)2017,Vol.16Issue(3):225-229,5.DOI:10.3969/j.issn.1674-232X.2017.03.001
n-Bu4NI/TBHP作用下水相中醛的高效氧化反应
Highly Efficient Oxidation of Aldehydes Mediated by n-Bu4NI/TBHP in Water
摘要
Abstract
A highly efficient oxidation of aromatic aldehydes to corresponding carboxylic acids by using TBHP as oxidant catalyzed by n-Bu4NI under mild reaction conditions is reported.The results show that the yield can reach 95% with water as the solvent in 6 h.Under the optimised reaction condition,a series of aldehydes are investigated,and the carboxylic acids can be obtained in more than 90% yields.关键词
醛/羧酸/水相/氧化反应Key words
aldehyde/carboxylic acid/aqueous media/oxidation reaction分类
化学化工引用本文复制引用
丁丽媛,高颖,曾晓飞,钟国富..n-Bu4NI/TBHP作用下水相中醛的高效氧化反应[J].杭州师范大学学报(自然科学版),2017,16(3):225-229,5.基金项目
浙江省公益技术研究社会发展项目(2016C33088) (2016C33088)
杭州市留学归国人员创新创业项目. ()