电池2016，Vol.46Issue(6)：298-301,4.
高温固相法制备高温锂电池用LiCr3O8
Preparing LiCr3O8 for lithium battery by high temperature solid state method
摘要
Abstract
The high temperature thermal stability of chromic acid lithium(LiCr3O8)prepared at different sintering temperatures and its chemical compatibility with the eutectic nitrate were analyzed,the electrochemical performance at different temperatures and current density of the battery composed of LiCr3O8 and Li-Mg-B alloy was tested.The high temperature thermal stability of LiCr3O8 obtained at all temperatures and the chemical compatibility with molten nitrate salts were good and they were suitable for high temperature lithium battery cathode materials.Raising the discharge temperature enhanced the reactivity,but increased the selfdischarge of the cell.LiCr3O8 prepared at 350 ℃ sintering showed the lowest internal resistance of the battery during discharge and suitable for the high temperature lithium battery cathode material working in the range of 200 ～ 300 ℃.关键词
锂电池/正极材料/热稳定性/化学相容性/亚铬酸锂(LiCr3O8)Key words
lithium battery/cathode material/thermal stability/chemical compatibility/chromic acid lithium(LiCr3O8)分类
信息技术与安全科学引用本文复制引用
苗会敏,吴铸,杜俊霖,夏保佳..高温固相法制备高温锂电池用LiCr3O8[J].电池,2016,46(6):298-301,4.基金项目
国家自然科学基金(21473234),上海市国内合作项目(16595800700) （21473234）
