北华大学学报（自然科学版）2017，Vol.18Issue(4)：439-444,6.DOI:10.11713/j.issn.1009-4822.2017.04.004
SDS对所制备的TiO2可见光催化活性的影响
Effects of SDS on Visible Light Photocatalytic Activities of the as-Prepared TiO2
摘要
Abstract
Titania photocatalysts(TPC) were successfully prepared by hydrolysis of TiCl4 in the presence of SDS.All of TPC were characterized by transmission electron microscopy(TEM),X-ray diffraction (XRD) analysis,UV-visible light spectra,and nitrogen adsorption/desorption.The results of photocatalytic activity test showed that all of TPC had better visible light photocatalytic activities than P25 for the photodegradation of methyl orange,and the visible light photocatalytic activity increased with the increase in the mole ratio of TiCl4 to SDS.SDS are helpful to regulate the distribution of high-energy oxo-bridging,so as to control visible light photocatalytic activities by regulating the intensity of interaction between particles.The exposed active facets is helpful to enhance its photocatalytic efficiency too.When the mole ratio of TiCl4 to SDS was 51.2,the methyl orange removal efficiency was up to 74.4% under visible light(35 W,common civilian illuminant) irradiation for 3 h.It would possess potential application prospect in self-cleaning interior building latex coating with photocatalysis.关键词
十二烷基磺酸钠/二氧化钛/可见光催化剂/甲基橙/高能氧桥键/自清洁内墙涂料Key words
sodium dodecanesulphonate(SDS)/titania/visible light photocatalysis/methyl orange(MO)/high-energy oxo-bridging/self-cleaning interior building latex coating分类
化学化工引用本文复制引用
石莉萍,刘纯,王丽君..SDS对所制备的TiO2可见光催化活性的影响[J].北华大学学报（自然科学版）,2017,18(4):439-444,6.基金项目
吉林省科技发展计划项目(201105042) （201105042）
吉林省教育厅科学技术研究项目(2014187) （2014187）
吉林市科技计划项目(201434007). （201434007）
