波谱学杂志2017，Vol.34Issue(2)：183-190,8.DOI:10.11938/cjmr20170207
呋喃阿洛糖衍生物水解产物的结构确定
Structural Elucidation of a Hydrolysis Product from Derivatives of Allofuranose
摘要
Abstract
1,2-O-(1-methylethylidene)-3-C-methylnitro-α-D-allofuranose(2)was obtained through selective deprotection of1,2;5,6-Di-O-isproplidene-3-C-methylnitro-α-D-allofuranose(1)underanacidic condition. C-3 nitrostyrenes(3)was synthetizedthrough Moffatt dehydration from compound1underanacidic condition.A hydrolysis product 1,2-O-(1-methylethylidene)-3-C-methylnitro-α-D-glocufuranose(2')which hada reversedC-3 configuration wasobtained by an unexpected oxa Michael addition.Compounds2and2'were C-3 diasteroisomers.Compound2'was characterized withNMR spectroscopy techniques, including1HNMR,13CNMR,DEPT-135,1H-1H COSY, gHSQC and gHMBC.1H and 13Cchemical shiftsof compound2'were also fullyassigned. The molecular structure of compound2'was determined.关键词
核磁共振(NMR)/归属/2D NMR/水解产物Key words
nuclear magnetic resonance (NMR)/assignment/2D NMR/hydrolysis product分类
数理科学引用本文复制引用
张恩,崔得运,孙伟,李鹏云,徐锦梅,刘宏民..呋喃阿洛糖衍生物水解产物的结构确定[J].波谱学杂志,2017,34(2):183-190,8.基金项目
国家自然科学基金资助项目(81172937,U1204206). （81172937,U1204206）
