含能材料2017，Vol.25Issue(6)：442-450,9.DOI:10.11943/j.issn.1006-9941.2017.06.001
含能金属有机骨架研究进展
Research Progress in Energetic Metal-organic Frameworks
摘要
Abstract
In recent years,energetic metal-organic frameworks(E-MOFs) have received worldwide research attention due to their promising characteristics of both high energy level and low sensitivity.The design and syntheses of new E-MOFs with new structures,high energy level and excellent safety property have become a research hotspot in the field of energetic materials.Up to now,the energetic organic ligands that have been used for the construction of E-MOFs can be classified into three major categories:small molecular energetic ligands (azide anion and hydrazine),nitrogen-rich heterocyclic ligands (triazole,tetrazole and derivative),energetic ligands with multiple explosophores (e.g.nitro group).According to above classification of three energetic ligands,in this paper,we briefly reviewed the recent advances of E-MOFs from the standpoints of their self-assembly strategies,energy level,and safety issues.After systemically analyzing above advances in the field of E-MOFs,it can be conclude that the rational design and selection of nitrogen-rich multbentate energetic ligand molecules and their self-assembly metal ions are the key to successfully construct novel E-MOFs,since different self-assembly methods will determine the topologies of the E-MOFs'networks and thereby significantly influence the physicochemical properties of the resulting E-MOFs.As a newly emerging class of energetic materials,E-MOFs have exhibited unique properties including high energy level and low sensitivity,demonstrating the important research value and development potential among the applications of solid propellant formulations and laser initiation fields.关键词
含能金属有机骨架(E-MOFs)/含能材料/有机配体/爆速/感度Key words
energetic metal-organic frameworks(E-MOFs)/energetic materials/organic ligands/detonation/sensitivity分类
军事科技引用本文复制引用
王帜,王毅,王康才,张庆华..含能金属有机骨架研究进展[J].含能材料,2017,25(6):442-450,9.基金项目
国家自然科学基金青年基金(21602211) （21602211）
中国工程物理研究院化工材料研究所一般授权项目(032700118003) （032700118003）
