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固相法合成NaA型粉煤灰沸石对染料废水的吸附性能研究

宋瑞然 肖敏 胡晓钧 刘月

人工晶体学报2017,Vol.46Issue(5):897-902,6.
人工晶体学报2017,Vol.46Issue(5):897-902,6.

固相法合成NaA型粉煤灰沸石对染料废水的吸附性能研究

Adsorption of Dye Wastewater by NaA Zeolite from Fly Ash bySolid Transformation Method

宋瑞然 1肖敏 2胡晓钧 3刘月2

作者信息

  • 1. 沈阳大学机械工程学院,沈阳 110044
  • 2. 沈阳大学环境学院,区域污染环境生态修复教育部重点实验室,沈阳 110044
  • 3. 上海应用技术大学化学与环境工程学院,上海 201418
  • 折叠

摘要

Abstract

Fly ash zeolite was synthesized by solid transformation method with coal fly ash.The effects of adsorption time, pH value and concentration of methylene blue (MB) solution, and adsorption temperature on the zeolite adsorption performance of MB were discussed by static adsorption experiment.The synthetical zeolite was characterized by means of SME and XRD.The results show that the synthetic product is NaA zeoite with hetero crystal by analysis of XRD.Analysis of SEM show that the product has spindle structure and cubic structure of NaA zeolite respectively.The removal rate of NaA zeolite can reach more than 90% for the initial concentration of 50-100 mg·L-1 of MB and it was 45% higher than fly ash at the adsorption temperature 25 ℃, pH>5, fly ash zeolite dosage 8 g·L-1, adsorption time 30 min.It is equivalent to commercial zeolite.The process about fly ash zeolite adsorb methylene blue conformed to the Langmuir model which is single molecular layer adsorption.

关键词

固相法/粉煤灰/NaA型沸石/吸附

Key words

solid transformation method/coal fly ash/NaA zeolite/adsorption

分类

资源环境

引用本文复制引用

宋瑞然,肖敏,胡晓钧,刘月..固相法合成NaA型粉煤灰沸石对染料废水的吸附性能研究[J].人工晶体学报,2017,46(5):897-902,6.

基金项目

沈阳市科技计划(F13-062-2-00) (F13-062-2-00)

辽宁省教育厅项目(L2015361) (L2015361)

国家科技支撑计划(2012BAD14B04-5) (2012BAD14B04-5)

人工晶体学报

OA北大核心CSCDCSTPCD

1000-985X

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