无机材料学报2017,Vol.32Issue(6):561-570,10.DOI:10.15541/jim20160479
新型二维材料MXene的研究进展
Research Progress of Novel Two-dimensional Material MXene
摘要
Abstract
MXene is a new family of two-dimensional transition metal carbides or carbonitrides with graphene-like 2D morphology. The chemical formula of MXene is Mn+1XnTz, where M is an early transition metal, X is C and/or N, T stands for surface-terminating functional groups like F-, OH-, O2-,etc., andn = 1, 2, or 3. It can be achieved by selective etching of the A element from the MAX phases, and HF is an etchant mostly used. First-principles calcu-lations about MXene have been performed to reveal the structure and properties. MXene has also been found to have a unique two-dimensional layered structure, large specific surface area and good electrical conductivity, stabil-ity, magnetic and mechanical properties, and thus it is promising in many fields, including energy storage, catalysis and adsorption. This article reviews the quite recent progress of MXene based on theoretical and experimental considera-tions, especially its structure, synthesis, and applications. Finally, the suggestions about existing challenges and future de-velopments are proposed. MXene is expected to be used for more various applications with further extensive research.关键词
MXene/化学液相蚀刻法/第一性原理计算/应用Key words
MXene/chemical liquid phase etching method/the first-principles calculation/application分类
化学化工引用本文复制引用
张建峰,曹惠杨,王红兵..新型二维材料MXene的研究进展[J].无机材料学报,2017,32(6):561-570,10.基金项目
江苏省自然科学基金(BK20161506) (BK20161506)
中央高校科研业务费(2013B34414, 2015B01914, 2016B45614) (2013B34414, 2015B01914, 2016B45614)
高性能陶瓷与超微结构国家重点实验室开放基金(SKL201401SIC) Jiangsu Provincial Natural Science Foundation of China (BK20161506) (SKL201401SIC)
Fundamental Research Funds for Central Universities(2013B34414, 2015B01914, 2016B45614) (2013B34414, 2015B01914, 2016B45614)
The Open Found From State Key Lab of High Performance Ceramics and Superfine Microstructure(SKL201401SIC) (SKL201401SIC)