表面技术2017,Vol.46Issue(5):209-214,6.DOI:10.16490/j.cnki.issn.1001-3660.2017.05.034
浸润性可转变的超疏水织物用于油水分离研究
Application of Superhydrophobic Fabric of Reversible Wettability in Oil-Water Separation
郭素明 1蔡再生 1牟晓峰2
作者信息
- 1. 东华大学 纺织面料技术教育部重点实验室,上海 201620
- 2. 上海纽恩特实业有限公司,上海 201400
- 折叠
摘要
Abstract
The work aims to prepare a superhydrophobic/superhydrophilic fabric of convertible wettability for oil-water se-paration. A micron-submicron structure was constructed on the surface of polyester/cotton fabric in the method of chemical copper-plating, then the fabric was immersed in dodecanoic acid ethanol solution to obtain superhydrophobic fabric. Surface morphology, element distribution and wettability of the polyester/cotton fabric were tested with scanning electron microscope (SEM), energy dispersive X-ray spectrometer (EDXS) and contact angle tester. The copper-plated polyester/cotton fabric mod-ified with the dodecanoic acid was of super hydrophobic property, and its contact angle with water was 151.9°. In addition, the reversible transition of wettability could be realized by changing pH of the environment where superhydrophobic fabric was, which could make oil-water seperation possible with separation efficiency of 98% and separation cycle index of over 80 times. Superhydrophobic fabric for oil/water separation can be successfully fabricated by constructing rough surface based on electro-less copper plating and modifying it with dodecanoic acid, a low surface energy substance. Superhydrophilic fabric can be ob-tained by increasing pH value of the environment where the fabric is. Both superhydrophobic and superhydrophilic fabrics can be used for oil-water separation.关键词
化学镀/超疏水/超亲水/油水分离Key words
chemical plating/superhydrophobic/superhydrophilic/oil-water separation分类
化学化工引用本文复制引用
郭素明,蔡再生,牟晓峰..浸润性可转变的超疏水织物用于油水分离研究[J].表面技术,2017,46(5):209-214,6.