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首页|期刊导航|火炸药学报|二十面体多硼氢B12H2-12阴离子化合物及其在火炸药中的应用研究进展

二十面体多硼氢B12H2-12阴离子化合物及其在火炸药中的应用研究进展

单自兴 绳利丽 杨荣杰

火炸药学报2017,Vol.40Issue(3):1-16,16.
火炸药学报2017,Vol.40Issue(3):1-16,16.DOI:10.14077/j.issn.1007-7812.2017.03.001

二十面体多硼氢B12H2-12阴离子化合物及其在火炸药中的应用研究进展

Research Progress of Icosahedronal Polyhydroborate B12H2-12 Anion Compounds and Their Application in Propellants and Explosives

单自兴 1绳利丽 2杨荣杰1

作者信息

  • 1. 北京理工大学材料学院,北京 100081
  • 2. 武汉大学化学学院,湖北 武汉 430072
  • 折叠

摘要

Abstract

The preparation, thermal behavior, thermochemistry, energy properties of icosahedronal closo-hydroborate anion B12H2-12 and related compounds in the study of propellants and explosives were systematically reviewed.The application prospect of this kind of polyhydroborate compounds in this field is prospected.Pointing out that based on theoretical calculation, taking the complete combustion of polyhydroborate compounds as target, the design, synthesis and screening of new B12H2-12 ion derivatives with high energy and ultra high energy of highly efficient release intrinsic energy in propellants and explosives system should be the main directions of future research in polyhydroborate compound propellants,with 158 references.

关键词

二十面体闭笼型氢硼酸盐/火炸药/硼氢化合物/B12H2-12/二十面体硼氢阴离子/十二氢十二硼酸盐

Key words

icosahedronal closo-hydroborate salt/propellants and explosives/polyhydroborate compounds/B12H2-12/icosahedronal polyhydroborate/dodecahydrododeca-borate salt

分类

军事科技

引用本文复制引用

单自兴,绳利丽,杨荣杰..二十面体多硼氢B12H2-12阴离子化合物及其在火炸药中的应用研究进展[J].火炸药学报,2017,40(3):1-16,16.

火炸药学报

OA北大核心CSCDCSTPCD

1007-7812

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