人工晶体学报2017，Vol.46Issue(6)：1170-1174,5.
二维锰(Ⅱ)配位聚合物[Mn2(bppc)4(H2O)]n·2nH2O的合成、晶体结构及热稳定性研究
Synthesis, Crystal Structure and Thermal Property of a 2D Coordination Polymer [Mn2(bppc)4(H2O)]n·2nH2O
摘要
Abstract
A manganese coordination polymer [Mn2(bppc)4(H2O)]n·2nH2O was hydrothermally synthesized by Hbppc with MnCl2 .The coordination polymer was structurally characterized by single crystal X-ray diffraction,elemental analyses,IR and TGA.X-ray diffraction analysis of single crystal shows that the coordination polymer is crystallized in Monoclinic system with P2(1)/c space group.The cell parameters are as follows a=10.3918(9) nm, b=24.519(2) nm, c=7.0140(6) nm, β=105.0890(10)°, γ=90°.Each (bppc)-anion coordinates to one MnII atoms are bridged by the nitrogen atoms and carboxylate oxygen atoms of (bppc)-ligands to form a one line-like dimensional chain, and the carboxylate oxygen atoms of (bppc)-ligands further extended the 1D chain into 2D layer structure.Additionally, TGA results indicate it possess great thermal stability.关键词
锰/水热法/配合物/晶体结构Key words
manganese/hydrothermal method/complex/crystal structure分类
化学化工引用本文复制引用
宋娟,葛红光..二维锰(Ⅱ)配位聚合物[Mn2(bppc)4(H2O)]n·2nH2O的合成、晶体结构及热稳定性研究[J].人工晶体学报,2017,46(6):1170-1174,5.基金项目
国家自然科学基金(21373132) （21373132）
陕西理工大学博士科研启动基金(SLGKYQD2-08) （SLGKYQD2-08）
