塑料科技2017，Vol.45Issue(7)：21-25,5.DOI:10.15925/j.cnki.issn1005-3360.2017.07.001
多省并醌聚合物的合成与表征
Synthesis and Characterization of Polyacene Quinone Radical Polymer
摘要
Abstract
Polyacene quinone radical polymer (PAQR) was synthesized by solid-state heating method,molten salt method and solvothermal method with anthraquinone (AQ) and pyromellitic dianhydride (PMA) as raw materials,and lewis acid as the catalyst.The structure of PAQR was analyzed by X-ray diffraction (XRD),Fourier transform infrared spectroscopy (FTIR),thermogravimetric analysis (TG) and element analyzer.The properties of PAQR were investigated through impedance analyzer.The results show that the PAQR synthesized by molten salt method can provide the higher yield,up to 42％.Meanwhile,the polymer synthesized by solvothermal method has the highest polymerization degree and conjugation degree,and the better dielectric property.关键词
多省并醌聚合物/溶剂热法/产率/介电性能Key words
Polyacene quinone radical polymer/Solvothermal method/Yield/Dielectric property分类
化学化工引用本文复制引用
陆周,钱旭东,周颖,叶旭初..多省并醌聚合物的合成与表征[J].塑料科技,2017,45(7):21-25,5.基金项目
国家重点研发计划(2016YFB0601500) （2016YFB0601500）
长江学者和创新团队发展计划资助项目(IRT1146) （IRT1146）
