陕西科技大学学报2017，Vol.35Issue(3)：101-105,137,6.
基于3-(3-羧基-苯氧基)邻苯二甲酸与Cd(Ⅱ)的配位聚合物的合成、结构及性质
Synthesis, crystal structures and properties of Cd-coordination polymers based on 3-(3-carboxy-phenoxy)phthalic acid
摘要
Abstract
In order to get with fluorescence property of coordination polymer.A coordination polymer based on a new tricarboxylate ligand 3-(3-carboxy-phenoxy)phthalic acid(H3 cppa)and cadmium(Ⅱ),namely [Cd(Hcppa) (H2O)2 (CH3OH)]n,has been successfully synthesized via solvothermal reactions under the condition of 145 ℃.The coordination polymer forms a three dimensional (3D) supramolecular structure linked by intermolecular hydrogen bonds based on 1D chains.Additionally,the compounds had the good thermal stability property and the strong fluorescence,and characterized by X-ray single crystal diffraction,FTIR,PXRD,TGA and fluorescence.关键词
3-(3-羧基-苯氧基)邻苯二甲酸/配合物/荧光Key words
3-(3-carboxy-phenoxy) phthalic acid/coordination polymer/fluorescenc分类
化学化工引用本文复制引用
张亚男,张鹏,殷海菊,成晶..基于3-(3-羧基-苯氧基)邻苯二甲酸与Cd(Ⅱ)的配位聚合物的合成、结构及性质[J].陕西科技大学学报,2017,35(3):101-105,137,6.基金项目
国家自然科学基金项目(21401121) （21401121）
陕西省科技厅科学技术研究发展计划项目(2014JQ2061) （2014JQ2061）
陕西省教育厅专项科研计划项目(15JK1109) （15JK1109）
陕西科技大学博士科研启动基金项目(BJ11-22) （BJ11-22）
