郑州大学学报（理学版）2017，Vol.49Issue(3)：93-98,6.DOI:10.13705/j.issn.1671-6841.2016264
三维铜配位聚合物的构筑、晶体结构及磁性质
Synthesis, Crystal Structure and Magnetic Properties of a 3D Cu Coordination Polymer
摘要
Abstract
A three-dimensional coordination polymer {[Cu34(2NG)26(DMF)6(H2O)12]·2H2O}n (complex 1) was prepared through the reaction of N-(2-naphthoyl)-amino acetic acid thiourea (2NGH3) with Cu(OAc)2·H2O in the solution of MeOH and DMF.Its molecular structure was preliminary characterized by infrared spectroscopy,elemental analysis and TG analyses,and further confirmed by X-ray single crystal diffraction.XPS analysis confirmed the existence of Cu(I) and Cu(Ⅱ) ions in complex 1.Magnetic measurement showed that the ferromagnetic coupling between the Cu(Ⅱ) ions in complex 1 could be observed.关键词
取代羧酸硫脲配体/铜(Ⅱ)/配位聚合物/晶体结构/性能Key words
substituted acylthiourea carboxylate ligand/Cu (Ⅱ)/coordination polymer/crystal structure/property分类
化学化工引用本文复制引用
冯俊阳,郭清,安子龙,李纲..三维铜配位聚合物的构筑、晶体结构及磁性质[J].郑州大学学报（理学版）,2017,49(3):93-98,6.基金项目
国家自然科学基金项目(21571156,J1210060) （21571156,J1210060）
河南省教育厅重点项目(18A150036). （18A150036）
