工程科学学报2017,Vol.39Issue(7):1047-1054,8.DOI:10.13374/j.issn2095-9389.2017.07.010
氧化膜对14Cr12Ni2WMoVNb钢QPQ渗层的室温摩擦磨损和腐蚀性能的影响
Effect of oxide film on tribological properties at room temperature and corrosion performance of QPQ nitride layers on 14Cr12Ni2WMoVNb steel
摘要
Abstract
This study analyzed the effects of the oxide film of 14Cr12Ni2WMoVNb steel with QPQ (quench-polish-quench) treatment on tribological properties at room temperature and corrosion resistance of the layers.The microstructure and properties of specimens with and without oxide film were studied by metallographic analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), a scratch tester, friction and wear tester, and at an electrochemical workstation.Results show that the effects of the oxide film on tribological properties of the layers are related to load.When the friction time is 4min and the load is low (50N), the friction coefficient of the oxide film and the volume wear rate are effectively decreased.However, with a friction time of 4min and a high load (100N), the oxide film is destroyed, there is thus no reduction in the volume wear rate.The study also shows that the oxide film obviously improves the corrosion resistance of the layers.The Tafel polarization curve of the specimen with oxide film has an obvious passivation region, and the pitting potential is-13mV.The surface of the specimen with the oxide film removed has a wide area of corrosion after salt spray corrosion for 12h, whereas a large area of corrosion only occurs after 48h of salt spray for the specimen with the oxide film.关键词
14Cr12Ni2WMoVNb钢/氧化膜/摩擦学性能/腐蚀性能Key words
14Cr12Ni2WMoVNb steel/oxide film/tribological properties/corrosion resistance分类
矿业与冶金引用本文复制引用
张乐,张津,余强,李洪,连勇,高文,任青松..氧化膜对14Cr12Ni2WMoVNb钢QPQ渗层的室温摩擦磨损和腐蚀性能的影响[J].工程科学学报,2017,39(7):1047-1054,8.基金项目
北京市腐蚀、磨蚀与表面技术重点实验室和北京市教委共建资助项目(SYS100080419) (SYS100080419)