华中师范大学学报（自然科学版）2017，Vol.51Issue(4)：470-478,9.DOI:10.19603/j.cnki.1000-1190.2017.04.010
三羟甲基丙烷油酸酯类润滑油的抗磨损性能研究
Study of antiwear properties of modified lubricant about trimethylolpropane trioleate
摘要
Abstract
Trimethylolpropane trioleate (TMPTO) was prepared as base oil along with a series of 4-quinazolone propionate as lubricant additives.The additives were dissolved in TMPTO with a concentration of 1wt.％,respectively.The antiwear property of modified lubricants were evaluated by using a microtribometer (UMT-3).Based on the theory of quantitative structure tribo-ability relationship (QSTR),the three-dimensional quantitative structure tribo-ability relationship (3D-QSTR) models of antiwear property about lubricant additives were established by comparative similarity indices analysis (CoMSIA) method.The results show that the antiwear properties of lubricant modified by 4 quinazolone pentyl propionate,4-quinazolone tetradecyl propionate,4-quinazolone pentadecyl propionate and 4-quinazolone hexadecyl propionate are good.The presence of branch carbon chain might have an adverse effect on the antiwear property for 4-quinazolone propionate.The CoMSIA models constructed by steric field and hydrophobic field have good prediction ability,which indicates that it will benefit antiwear activity if the specific molecular groups present in the particular areas.关键词
三羟甲基丙烷油酸酯/4喹唑啉酮丙酸酯/抗磨损性能/摩擦学定量构效关系/比较分子相似性指数分析Key words
trimethylolpropane trioleate/4-quinazolone propionate/antiwear property/quantitative structure tribo-ability relationship/comparative similarity indices analysis分类
化学化工引用本文复制引用
杨奇,张维农,高新蕾..三羟甲基丙烷油酸酯类润滑油的抗磨损性能研究[J].华中师范大学学报（自然科学版）,2017,51(4):470-478,9.基金项目
国家自然科学基金项目(51675395) （51675395）
湖北省高等学校优秀中青年科技创新团队计划项目(T201709). （T201709）
