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微米金刚石负载纳米银的电化学性能

孟为民 黄浩 郭松 马喜龙

金刚石与磨料磨具工程2017,Vol.37Issue(2):20-25,6.
金刚石与磨料磨具工程2017,Vol.37Issue(2):20-25,6.DOI:10.13394/j.cnki.jgszz.2017.2.0005

微米金刚石负载纳米银的电化学性能

Electrochemical performance of Ag-coated micron diamond

孟为民 1黄浩 1郭松 2马喜龙1

作者信息

  • 1. 河南黄河旋风股份有限公司,河南长葛461501
  • 2. 燕山大学材料科学与工程学院,河北秦皇岛066004
  • 折叠

摘要

Abstract

Micro diamond possesses excellent physical and chemical properties.In order to expand its application field,nano silver particles were coated on the surface of micro diamond by glucose reducing complexation Ag+ in silver ammonia solution.The morphology,composition and structure of composites were characterized by SEM,TEM,EDS and XRD.The properties of oxygen reduction and oxygen evolution of diamond with different content of coated Ag were studied by using rotating disk electrodes.Results show that the limiting current density of oxygen reduction reaction is 4.1 mA/cm2,while the limiting current density of oxygen evolution reaction is 27.5 mA/cm-2 when the silver mass fraction is 10%.

关键词

氧还原/析氧反应/极限电流密度

Key words

oxygen reduction reaction/oxygen evolution/limiting current density

分类

化学化工

引用本文复制引用

孟为民,黄浩,郭松,马喜龙..微米金刚石负载纳米银的电化学性能[J].金刚石与磨料磨具工程,2017,37(2):20-25,6.

基金项目

中国博士后基金面上项目(2015M582191) (2015M582191)

河北省自然科学基金面上项目(E2017203160) (E2017203160)

河北省科技计划项目(16211118) (16211118)

河北省教育厅高等学校科技计划重点项目(ZD2017073). (ZD2017073)

金刚石与磨料磨具工程

OA北大核心CSTPCD

1006-852X

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