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PVP-SDS缔合行为与pH及比浓黏度的关系

吴业帆 奚丽莎 方云 林梦楚 李秀秀 翟然

日用化学工业2017,Vol.47Issue(7):361-364,4.
日用化学工业2017,Vol.47Issue(7):361-364,4.DOI:10.13218/j.cnki.csdc.2017.07.001

PVP-SDS缔合行为与pH及比浓黏度的关系

Relationship between association behavior of PVP - SDS and the change of pH or reduced specific viscosity

吴业帆 1奚丽莎 1方云 1林梦楚 1李秀秀 1翟然1

作者信息

  • 1. 江南大学化学与材料工程学院合成与生物胶体教育部重点实验室,江苏无锡 214122
  • 折叠

摘要

Abstract

Methods by means of pH and reduced specific viscosity measurement were established to study polyvinylpyrrolidone (PVP)- sodium dodecylsulfate (SDS)association under various concentrations of SDS since pH and viscosity of the system are sensitive to aggregation behaviors.It is the fact that double critical concentrations of SDS in the PVP-SDS association can be characterized by both methods.The reduced specific viscosity method is more sensitive and accurate than the pH method for both the minimum and the maximum values appeared on reduced specific viscosity plots corresponding to double critical concentrations of SDS,whereas the advantage of the pH method is to support the important effect of hydrogen ion on establishment of the PVP-SDS association.

关键词

十二烷基硫酸钠/聚乙烯吡咯烷酮/临界浓度/pH/比浓黏度

Key words

sodium dodecylsulfate/polyvinylpyrrolidone/critical concentration/pH/reduced specific viscosity

分类

化学化工

引用本文复制引用

吴业帆,奚丽莎,方云,林梦楚,李秀秀,翟然..PVP-SDS缔合行为与pH及比浓黏度的关系[J].日用化学工业,2017,47(7):361-364,4.

基金项目

"十二五"科技支撑计划资助项目(2014BAE03B01-1) (2014BAE03B01-1)

江苏省普通高校研究生科研创新计划资助项目(CXZZ13_0745) (CXZZ13_0745)

江南大学博士研究生科学研究基金资助项目(JUDCF13019) (JUDCF13019)

日用化学工业

OA北大核心CSCDCSTPCD

1001-1803

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