日用化学工业2017，Vol.47Issue(7)：365-368,4.DOI:10.13218/j.cnki.csdc.2017.07.002
离子液体表面活性剂的合成与应用(Ⅶ)——在化学反应中的应用
Synthesis and application of ionic liquid surfactants (Ⅶ) Applications of ionic liquid surfactants in chemical reactions
摘要
Abstract
Because of the dual properties of organic solvent and excellent surface activity,ionic liquid surfactants are used to accelerate chemical reactions.Enzymatic reaction is enhanced with improved enzyme activity greatly by ionic liquid surfactants.Lewis acidic and Br?nsted acidic ionic liquid surfactants are used to catalyze Ullmann-type coupling and esterification reactions.Poly-metal salts of oxy-acid or per-oxy acid, in combination with surfactant has been used separately to catalyze oxidation desulfurization of petroleum fractions and epoxidation of oleffins.CO2 hydrate is quickly formed by decreasing of the surface tension with ionic liquid surfactants and template action of cyclic cationics.关键词
表面活性剂/离子液体/催化/酶/化学反应Key words
surfactant/ionic liquid/catalysis/enzyme/chemical reaction分类
化学化工引用本文复制引用
徐清杰,杨许召,王萍,邹文苑,王军..离子液体表面活性剂的合成与应用(Ⅶ)——在化学反应中的应用[J].日用化学工业,2017,47(7):365-368,4.基金项目
"十二五"国家科技支撑计划资助项目(2013BAC01B04) （2013BAC01B04）
国家自然科学基金资助项目(21176228) （21176228）
河南省科技攻关项目(162102210056) （162102210056）
郑州市科技攻关项目(141PQYJS555) （141PQYJS555）
