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锰酸锂电池掺杂钴镍对电化学性能影响研究

李小庆 王晶 刘正实

电源技术2017,Vol.41Issue(7):987-988,2.
电源技术2017,Vol.41Issue(7):987-988,2.

锰酸锂电池掺杂钴镍对电化学性能影响研究

Effects of cobalt and nickel doping on electrochemical performance of LiMn2O4 batteries

李小庆 1王晶 2刘正实3

作者信息

  • 1. 重庆化工职业学院化学工程系,重庆400020
  • 2. 重庆大学化学化工学院,重庆400044
  • 3. 重庆市渝北区环境监测站,重庆400020
  • 折叠

摘要

Abstract

Lithium battery cathode materials were doped with cobalt and nickel through the sintering process,and also the pure phase lithium batteries were prepared.The composition,micro morphology,structure and charge discharge characteristics of the products were characterized by X ray diffraction,plasma emission spectrometer,electrochemical performance test system and electron scanning electron microscope.The study results show that lithium manganese battery doped with cobalt and nickel has high crystallinity,uniform particle and no obvious impurity phase.The initial discharge specific capacities of lithium battery doped with cobalt and nickel are 118.5,108.2 mAh/g capacity,respectively.After 50 cycles,the discharge specific capacity is 110.8,101.9 mAh/g,and the capacity retention is 93.5% and 94.2%,respectively.

关键词

锰酸锂电池/掺杂钴和镍/电化学性能/放电比容量

Key words

LiMn2O4 batteries/doping cobalt and nickel/electrochemical performance/discharge capacity

分类

信息技术与安全科学

引用本文复制引用

李小庆,王晶,刘正实..锰酸锂电池掺杂钴镍对电化学性能影响研究[J].电源技术,2017,41(7):987-988,2.

基金项目

重庆市教委科学技术研究项目(KJ1504402) (KJ1504402)

电源技术

OA北大核心CSCDCSTPCD

1002-087X

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