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组合抑制剂CCSL浮选分离PbS、ZnS与单斜Fe1-x S的研究

白安平 宋永胜 周鹤

工程科学学报2017,Vol.39Issue(8):1152-1158,7.
工程科学学报2017,Vol.39Issue(8):1152-1158,7.DOI:10.13374/j.issn2095-9389.2017.08.003

组合抑制剂CCSL浮选分离PbS、ZnS与单斜Fe1-x S的研究

Floatation separation of galena, sphalerite, and pyrrhotite by combined depressant CCSL

白安平 1宋永胜 1周鹤1

作者信息

  • 1. 北京有色金属研究总院生物冶金国家工程实验室, 北京 100088
  • 折叠

摘要

Abstract

The flotation separation of galena, sphalerite, and pyrrhotite was investigated with CCSL as a depressant. Flotation test results show that galena and sphalerite can float but pyrrhotite can barely float with CCSL as a depressant. The flotation tests also show that galena can be separated efficiently from pyrrhotite, and that sphalerite can be separated on the whole from pyrrhotite, but the separation efficiency of the former is much better. The X-ray photoelectron spectroscopy (XPS), IR spectrum, and Zeta potential analysis results indicate that the interaction of sodium acetate and pyrrhotite is not only physical absorption. The UV spectrum indicates that the decline in floatability of pyrrhotite is due to the hydrophilicity caused by CH3 COO - being stronger than that caused by dixan-thogen, and the xanthate adsorption on pyrrhotite is not prohibited by CH3 COO - . The CH3 COO - reacts not only with pyrrhotite, but also with H + in water as a H-bond, so the pyrrhotite becomes hydrophilic.

关键词

CCSL/磁黄铁矿/方铅矿/闪锌矿/浮选分离

Key words

CCSL/pyrrhotite/galena/sphalerite/flotation separation

分类

矿业与冶金

引用本文复制引用

白安平,宋永胜,周鹤..组合抑制剂CCSL浮选分离PbS、ZnS与单斜Fe1-x S的研究[J].工程科学学报,2017,39(8):1152-1158,7.

基金项目

国家科技支撑计划资助项目(2015BAB12B00) (2015BAB12B00)

工程科学学报

OA北大核心CSCDCSTPCD

2095-9389

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