华东理工大学学报（自然科学版）2017，Vol.43Issue(4)：509-515,7.DOI:10.14135/j.cnki.1006-3080.2017.04.009
锂离子电池中苯衍生物氧化还原穿梭分子的一种稳定性模型:同时考虑成键/断键反应和还原反应
A Stability Model for Benzene Derivative Redox Shuttles in Lithium-Ion Batteries:Including both Bond Forming/Breaking Reactions and Reduction Reactions
陈建华 1谢湘华 1朱云霞 1张孟 1贺黎明 1王良琛1
作者信息
摘要
Abstract
A stability model is presented for the benzene derivative redox shuttles in lithium-ion batteries.This model takes both bond forming/breaking reactions and reduction reactions of redox shuttles in batteries into account and obtains a very good linear correlation between the experimental numbers of 100% shuttle-protected overcharge cycles in logarithm scale and the combined reactivity indexes,Eb (ER)+0.3Eb (Li),where the values of Eb (ER) and Eb (Li) are the binding energy of the redox shuttle cation in the model reactions with an ethyl radical (ER) and a Li atom in bulk,respectively.关键词
锂离子电池/苯衍生物/氧化还原穿梭分子/稳定性模型Key words
lithium-ion battery/benzene derivative/redox shuttle/stability model分类
数理科学引用本文复制引用
陈建华,谢湘华,朱云霞,张孟,贺黎明,王良琛..锂离子电池中苯衍生物氧化还原穿梭分子的一种稳定性模型:同时考虑成键/断键反应和还原反应[J].华东理工大学学报（自然科学版）,2017,43(4):509-515,7.
