高校化学工程学报2017，Vol.31Issue(4)：763-768,6.DOI:10.3969/j.issn.1003-9015.2017.04.002
从废水溶液中络合萃取N-羟基丁二酰亚胺的研究
Complexation Extraction of N-Hydroxysuccinimide from Wastewater
高鲁友 1王文弘 1彭阳峰 1张卫东2
作者信息
- 1. 华东理工大学 化工学院, 上海 200237
- 2. 东台市 东靖医化科技有限公司, 江苏 盐城 224200
- 折叠
摘要
Abstract
A complex extraction solvent composed of tri-n-octylamine (TOA) and n-butanol was used to separate N-hydroxysuccinimide (HOSU) from HOSU containing solutions (concentration: 0.015~0.03 g·mL-1). The optimal extraction system was obtained using a single-stage equilibrium apparatus. Effects of TOA volume ratio, oil to water volume ratio, extraction temperature and sailing-out agent on the distribution coefficients of HOSU between oil and water phases were investigated, and liquid-liquid equilibrium data was measured at 25℃. Infrared spectroscopic results show that TOA-HOSU complexes are formed via hydrogen and ionic bonding. A mathematical model based on mass balance is developed to describe extraction equilibrium and correlate experimental equilibrium data at 25℃. The results show that the calculated HOSU concentrations in the organic phase are in good agreement with experimental data.关键词
N-羟基丁二酰亚胺/三辛胺/正丁醇/萃取/络合萃取Key words
N-hydroxysuccinimide/tri-n-octylamine/n-butanol/extraction/complexation extraction分类
化学化工引用本文复制引用
高鲁友,王文弘,彭阳峰,张卫东..从废水溶液中络合萃取N-羟基丁二酰亚胺的研究[J].高校化学工程学报,2017,31(4):763-768,6.
