化工进展2017，Vol.36Issue(9)：3135-3144,10.DOI:10.16085/j.issn.1000-6613.2017-0462
聚烯烃类弹性体——现状与进展
State-of-the-art and research progress of polyolefin-based elastomer
摘要
Abstract
In this review,state-of-the-art technology of polyolefin-based elastomer manufacture, including major producers and product trademarks,grades and properties were summarized. Research and developments on production process and catalyst system for the ethylene-propylene binary and ternary rubbers(EPM,EPDM,mEPDM),the poly(ethylene-co-α-olefin) elastomer(POE)and the poly(ethylene-block-α-olefin) elastomer(OBC)were also introduced. It has been pointed out that the thermoplastic elastomer,such as POE and OBC,and the polyolefin plastomer not only had excellent mechanical and physical properties of polyolefin-based elastomer,but also was easy molding and processing,and can be recycled and reused. And the metallocene catalyst had the advantages of high activity,good ability to catalyze copolymerization withα-olefin,and single active site. In order to independently develop the polyolefin-based elastomer,the thermoplastic elastomer and plastomer with more excellent performance and more profitable,such as mEPDM,POE and OBC et al,the researches on the metallocene catalyst with high temperature adaptability and the high temperature solution polymerization process must be strengthened.关键词
聚合物/生产/合成/弹性体/聚合/催化剂Key words
polymer/production/synthesis/elastomer/polymerization/catalyst分类
化学化工引用本文复制引用
李伯耿,张明轩,刘伟峰,王文俊..聚烯烃类弹性体——现状与进展[J].化工进展,2017,36(9):3135-3144,10.基金项目
国家自然科学基金重点项目(21536011)及国家重点基础研究发展计划项目(2011CB606000). （21536011）
