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双季铵盐改性纳米SiO2的乳化性能研究

黄威华 邹华 赖璐 梅平

日用化学工业2017,Vol.47Issue(8):430-434,439,6.
日用化学工业2017,Vol.47Issue(8):430-434,439,6.DOI:10.13218/j.cnki.csdc.2017.08.003

双季铵盐改性纳米SiO2的乳化性能研究

Studies on the emulsifying performance of nano-SiO2 particles modified with bis-quaternary ammonium salts

黄威华 1邹华 1赖璐 1梅平2

作者信息

  • 1. 长江大学化学与环境工程学院,湖北荆州434023
  • 2. 非常规油气湖北省协同创新中心,湖北武汉430100
  • 折叠

摘要

Abstract

Bis-quaternary ammonium salts BQAS-16 were used for the surface modification of nano-SiO2 particles,and the modified SiO2 nanoparticles were used as emulsifying agent for preparation of Pickering emulsion. Effects of the ratio of modification,the pH value,the addition of salt and the volume ratio of oil to water on the stability of Pickering emulsion were examined. Results show that the nano-SiO2 particles modified by BQAS-16 display better emulsifying performance as comparing with the nano-SiO2 particles. The stability of emulsion increases with increasing of the dosage of BQAS-16. With increasing the pH value, the stability of emulsion is basically no change. However,at the pH = 13,the stability of emulsion decreases significantly. Moreover,as the NaCl dosage increases,the stability of emulsion is basically no change. When the volume ratio of oil to water is 1: 1,the emulsion is at the most stable state.

关键词

双季铵盐/纳米SiO2/Pickering乳液/乳化性能

Key words

bis-quaternary ammonium salts/nano-SiO2 particles/Pickering emulsion/emulsifying performance

分类

化学化工

引用本文复制引用

黄威华,邹华,赖璐,梅平..双季铵盐改性纳米SiO2的乳化性能研究[J].日用化学工业,2017,47(8):430-434,439,6.

基金项目

国家自然科学基金资助项目(21403017) (21403017)

中国石油科技创新基金资助项目(2011D-5006-0211) (2011D-5006-0211)

日用化学工业

OA北大核心CSCDCSTPCD

1001-1803

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