石油化工2017，Vol.46Issue(5)：637-642,6.DOI:10.3969/j.issn.1000-8144.2017.05.019
CO2催化加氢制备甲醇的研究进展
Progresses in the research for the catalytic hydrogenation of carbon dioxide to methanol
摘要
Abstract
The catalytic hydrogenation of carbon dioxide to methanol is considered as one of the ideal ways to utilize carbon dioxide effectively,and the efficient catalysts are the key for increasing the conversion of carbon dioxide and the selectivity to methanol. In this paper,the catalytic reaction mechanism for the catalytic hydrogenation was summarized. The influences of the valence state, crystal structure and composition of copper-based catalysts on the catalyst performances were discussed,and the effects of ZnO as cocatalyst and support on the performances of the Cu/ZnO catalysts were analyzed. The advantages and disadvantages of the preparation methods were introduced.关键词
甲醇/CO2加氢/催化加氢/反应机理Key words
methanol/carbon dioxide hydrogenation/catalytic hydrogenation/reaction mechanism分类
化学化工引用本文复制引用
张香玲,马清祥,赵天生,耿梦倩,李鹏..CO2催化加氢制备甲醇的研究进展[J].石油化工,2017,46(5):637-642,6.基金项目
国家自然科学基金项目(21466030) （21466030）
宁夏科技支撑计划项目(2015BY113) （2015BY113）
宁夏自然科学基金项目(NZ13044). （NZ13044）
