印染助剂2017，Vol.34Issue(8)：38-40,3.
对叔丁基甲苯催化氧化合成对叔丁基苯甲醛工艺研究
Synthesis process of catalytic oxidation of 4-tert-
butylbenzaldehyde from 4-tert-butyltoluene
张金峰1
作者信息
- 1. 陕西省石油化工研究设计院,陕西省石油精细化学品重点实验室,陕西西安 710054
- 折叠
摘要
Abstract
4-Tert-butylbenzaldehyde were synthesized by heterogeneous catalyst and using oxygen as oxidant. According to the single factor experiment, the synthesis conditions were optimized. The optimal process was as follows: 4-tert-butyltoluene 1.0 g, acetonitrile 15 mL, catalyst 0.15 g, reaction temperature 60 ℃, reaction time 7 h, oxygen was 2 mL/min, N-hydroxyphthalimide 0.06 g. The yield of 4-tert-butylbenzaldehyde reached above 38%. The synthesis process could realize continuous production by using fixed bed, which was beneficial to environmental protection. So the process had a good application prospect.关键词
对叔丁基甲苯/对叔丁基苯甲醛/催化氧化Key words
4-tert-butyltoluene/4-tert-butylbenzaldehyde/catalytic oxidation分类
化学化工引用本文复制引用
张金峰..对叔丁基甲苯催化氧化合成对叔丁基苯甲醛工艺研究[J].印染助剂,2017,34(8):38-40,3.
