分析测试学报2017，Vol.36Issue(7)：849-857,9.DOI:10.3969/j.issn.1004-4957.2017.07.002
QuEChERS/超高效液相色谱-串联质谱法测定果蔬中122种香港规例农药残留
Determination of 122 Pesticide Residues in Fruits and Vegetables from Regulation of Pesticides in Hong Kong by QuEChERS Combined with Ultra Performance Liquid Chromatography-Tandem Mass Spectrometry
摘要
Abstract
A method for the determination of 122 pesticide residues in fruits and vegetables from the Hong Kong's regulation was developed by QuEChERS combined with ultra performance liquid chromatography-tandem mass spectrometry(UPLC-MS/MS).The quantification and confirmation was achieved by electrospray ionization (ESI) in positive and negative ion mode using multiple reaction monitoring (MRM) mode,and the analytes were quantified by the external standard method.The standard curves of 122 target compounds were linear in the range of 0.010-0.20 mg/L,with correlation coefficients(r) not less than 0.99.The limits of quantitation(LOQ) were 0.010 mg/kg.The recoveries at three spiked levels were in the range of 60％-110％ with RSDs of 1.8％ and 19.4％.The method had the advantages of rapidness,simplicity,time-saving,high sensitivity and good stability,and could significantly reduce the test cost.关键词
QuEChERS/超高效液相色谱-电喷雾串联质谱/农药残留Key words
QuEChERS/ultra performance liquid chromatography-tandem mass spectrometry(UPLC-MS/MS)/pesticide residues分类
化学化工引用本文复制引用
张建莹,邓慧芬,李月梅,林珊,岳振峰,吴卫东..QuEChERS/超高效液相色谱-串联质谱法测定果蔬中122种香港规例农药残留[J].分析测试学报,2017,36(7):849-857,9.基金项目
国家质检总局项目(2016IK240) （2016IK240）
