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PVA/GA/β-CD纳米纤维的制备及染料吸附性能

鲁冠秀 刘庆文 孔祥怡 丛乐乐 宋岩 赵晴 杨清彪 李耀先

高等学校化学学报2017,Vol.38Issue(8):1465-1469,5.
高等学校化学学报2017,Vol.38Issue(8):1465-1469,5.DOI:10.7503/cjcu20170142

PVA/GA/β-CD纳米纤维的制备及染料吸附性能

Preparation of PVA/GA/β-CD Nanofibers and Its Adsorption of Dyestuff

鲁冠秀 1刘庆文 2孔祥怡 2丛乐乐 1宋岩 1赵晴 3杨清彪 1李耀先2

作者信息

  • 1. 吉林大学中日联谊医院, 长春 130031
  • 2. 吉林大学化学学院, 长春 130021
  • 3. 吉林化工学院材料科学与工程学院, 吉林 132022
  • 折叠

摘要

Abstract

The polyvinylalcohol/β-cyclodextrin(PVA/β-CD) nanofibers with 70%(mass fraction) of β-CD were obtained by electrostatic spinning with hexafluoroisopropanol(HFIP) and H2O as solvents.And after cross-linking treatment with glutaraldehyde(GA), a water-insoluble nanofiber membrane of PVA/GA/β-CD was prepared.Compared with the products before being cross-linking, composition and morphology for the nanofibers were studied by Infrared spectroscopy and scanning electron microscopy.In addition, the adsorptive properties of the PVA/GA/β-CD nanofibers to seven water-soluble dyes were investigated.The results show that the adsorptive effect of fiber on malachite green, methyl violet and congo red are better than others, and the maximum adsorptive capacities are 124.71, 121.14 and 127.39 mg/g, respectively.After four cycles of adsorption-desorption, the dye removal rate still remains 80%.Thus, the nanofiber exhibits an excellent {applicative} prospect in waste water treatment with dye.

关键词

纳米纤维/静电纺丝/环糊精/染料吸附性能

Key words

Nanofiber/Electrospinning/Cyclodextrin/Adsorption of dyestuff

分类

化学化工

引用本文复制引用

鲁冠秀,刘庆文,孔祥怡,丛乐乐,宋岩,赵晴,杨清彪,李耀先..PVA/GA/β-CD纳米纤维的制备及染料吸附性能[J].高等学校化学学报,2017,38(8):1465-1469,5.

基金项目

吉林省自然科学基金(批准号: 20160101311JC, 20170101105JC)和吉林省科技厅重点项目(批准号: 20140204054GX, 20170204039GX)资助.Supported by the Natural Science Foundation of Jilin Province, China(Nos.20160101311JC, 20170101105JC) and the Key Projects of {Science} and Technology Department of Jilin Province, China(Nos.20140204054GX, 20170204039GX). (批准号: 20160101311JC, 20170101105JC)

高等学校化学学报

OA北大核心CSCDCSTPCD

0251-0790

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