化工进展2017，Vol.36Issue(8)：2924-2933,10.DOI:10.16085/j.issn.1000-6613.2016-2446
超临界二氧化碳中合成环碳酸酯的催化剂研究进展
Progress in synthesis of cyclic carbonates under supercritical carbon dioxide
摘要
Abstract
Supercritical carbon dioxide (scCO2) has been widely used as an environmentally friendly solvent to replace the conventional organic solvent in green chemical processes.Among those applications reported,the synthesis of cyclic carbonates from epoxides in supercritical CO2 has received a great interest.This review covered the recent progress in the synthesis of cyclic carbonates under supercritical carbon dioxide,with an emphasis on the state of the art of different kinds of catalysts employed in this reaction,including metal complex,quaternary onium salts,binary catalytic systems,ionic liquids,metal oxide,organocatalysts,et al.Furthermore,the advantages of supercritical carbon dioxide both as solvent and as reactant for this transformation were highlighted.From the economic and environmental point of view,organic catalysts,such as ionic liquids and quatemary onium salts,show promising potential application in the future development of chemical industry.It was also pointed out that the design and preparation of efficient and green catalysts are critical to this research field.关键词
超临界二氧化碳/环碳酸酯/环氧化物/催化Key words
supercritical carbon dioxide/epoxides/cyclic carbonates/catalysis分类
化学化工引用本文复制引用
范芳君,张治国,邢华斌,杨启炜,鲍宗必,杨亦文,任其龙..超临界二氧化碳中合成环碳酸酯的催化剂研究进展[J].化工进展,2017,36(8):2924-2933,10.基金项目
中央高校基本业务费项目(2016FZA4019). （2016FZA4019）
