分析化学2017，Vol.45Issue(9)：1339-1345,7.DOI:10.11895/j.issn.0253-3820.170158
苯基键合高比表面积活性炭的制备及其对挥发性有机化合物的吸附性能研究
Preparation of Phenyl-bonded High Specific Surface Area Activated Carbon and Its Adsorption to Volatile Organic Compounds
摘要
Abstract
The activated carbon with high specific surface area was prepared by carbonization with walnut shell as raw material and activation by potassium hydroxide.The surface of activated carbon was then modified by phenyltrimethoxysilane to prepare phenyl-bonded high specific surface area activated carbon adsorption material.The specific surface area and pore size distribution of phenyl-bonded activated carbon were measured by nitrogen adsorption method.The organic functional groups of the phenyl-bonded activated carbon, the chemical environment of the surface elements and the crystal structure were characterized by infrared spectroscopy, X-ray photoelectron spectroscopy and X-ray powder diffraction method.The volatile organic compounds (VOCs) in the air were absorbed by a sampling tube filled with the adsorption material prepared here, then desorbed into carbon disulfide solution and detected by gas chromatography.The saturated adsorption capacities of phenyl bonded activated carbon to 7 kinds of VOCs (ethanol, acetone, hexane, ethyl acetate, tetrahydrofuran, 1,2-dichloroethane, benzene) were in the range of 129-216 mg/g.In the range of 0.05-2.50 mg/mL, there was a good linear relationship between the peak height of the 7 components and the concentration, and the detection limits were in the range of 0.92-3.60 mg/m3.关键词
核桃壳/高比表面积活性炭/苯基键合改性/挥发性有机化合物/气相色谱Key words
Walnut shell/High specific surface area activated carbon/Phenyl bonded modification/Volatile organic compounds/Gas chromatography引用本文复制引用
吕伟超,申书昌,孙忠慧..苯基键合高比表面积活性炭的制备及其对挥发性有机化合物的吸附性能研究[J].分析化学,2017,45(9):1339-1345,7.基金项目
本文系黑龙江省自然科学基金项目(No.B201101)资助 （No.B201101）
