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可用于去除高盐废水中有机污染物的混凝-Fenton氧化联合工艺

时钰 杨晓芳 杨招艺 王东升 赵朝成

环境工程学报2017,Vol.11Issue(9):4958-4964,7.
环境工程学报2017,Vol.11Issue(9):4958-4964,7.DOI:10.12030/j.cjee.201701090

可用于去除高盐废水中有机污染物的混凝-Fenton氧化联合工艺

Organic pollutant removal from high-salinity wastewater by coagulation-Fenton integrated process

时钰 1杨晓芳 2杨招艺 1王东升 3赵朝成1

作者信息

  • 1. 中国科学院生态环境研究中心环境水质学国家重点实验室,北京100085
  • 2. 中国石油大学(华东)化学工程学院,青岛266580
  • 3. 北京环球中科水务科技有限公司,北京100085
  • 折叠

摘要

Abstract

The removal of organics from high salinity epoxy resin manufacturing wastewater by coagulation and Fenton processes was investigated and compared.The effects of initial pH value, Fenton's reagent or coagulant dosage and reaction time on organics removal were investigated during the oxidation and coagulation processes.Results showed that the optimum conditions for Fenton oxidation were obtained at pH =3 and the mole ratio of Fenton's reagent was n(Fe2+)/n(H2O2) =1 ∶ 20, Fe2+ dosage of 25 mmol · L-1, and H2O2 dosage of 500mmol · L-1.The maximum removal efficiency for TOC by Fenton oxidation was 62.50% after 120 min reaction.The removal efficiency of TOC by coagulation process was 23.78% with 300 mg· L-1dosage of FeSO4.The removal efficiencies of TOC in different Fenton and coagulation integrated processes, namely Fenton-coagulation(without addition of coagulant) process, Fenton-coagulation process, coagulation-Fenton oxidation and coagulation-two staged Fenton oxidation process, were 68.32% ,71.51% ,80.69% and 89.27% , respectively.

关键词

高盐有机废水/Fenton氧化/混凝-Fenton氧化

Key words

high salinity resin wastewater/Fenton oxidation/coagulation-Fenton oxidation

分类

资源环境

引用本文复制引用

时钰,杨晓芳,杨招艺,王东升,赵朝成..可用于去除高盐废水中有机污染物的混凝-Fenton氧化联合工艺[J].环境工程学报,2017,11(9):4958-4964,7.

基金项目

国家自然科学基金资助项目(21577160,51338010) (21577160,51338010)

环境工程学报

OA北大核心CSCDCSTPCD

1673-9108

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