人工晶体学报2017,Vol.46Issue(8):1569-1574,6.
微波对Cu-ZSM-5催化剂结构及低温NH3-SCR脱硝活性的影响
Influence of Microwave on the Structure and NH3-SCR Denitration Activity of Cu-ZSM-5 Catalysts
唐剑骁 1马丽萍 1王冬东 1王倩倩1
作者信息
- 1. 昆明理工大学环境科学与工程学院,昆明 650500
- 折叠
摘要
Abstract
Copper-based ZSM-5 zeolite catalysts were prepared using different ways of drying, the microwave drying and the conventional way, that is, electric blasting drying, based on incipient wetness impregnation method.XRD and N2 physisorption techniques were employed to investigate the effect of drying method on porous structure, phase structure as well as catalytic activity.The results show that copper introduction significantly promotes the catalytic activity;below 200 ℃ the catalytic activity of the microwave-dried M-4Cu-ZSM-5 is slightly higher than the conventionally-dried 4Cu-ZSM-5, while between 200-300 ℃ the latter exhibites superior catalytic performance;porous structure, crystal size and distribution of the active species of the catalyst were directly affected by the microwave treatment, causing the differences in catalytic activity.关键词
SCR/干燥方法/微波/铜基分子筛Key words
SCR/drying method/microwave/copper-based zeolite分类
化学化工引用本文复制引用
唐剑骁,马丽萍,王冬东,王倩倩..微波对Cu-ZSM-5催化剂结构及低温NH3-SCR脱硝活性的影响[J].人工晶体学报,2017,46(8):1569-1574,6.