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微波对Cu-ZSM-5催化剂结构及低温NH3-SCR脱硝活性的影响

唐剑骁 马丽萍 王冬东 王倩倩

人工晶体学报2017,Vol.46Issue(8):1569-1574,6.
人工晶体学报2017,Vol.46Issue(8):1569-1574,6.

微波对Cu-ZSM-5催化剂结构及低温NH3-SCR脱硝活性的影响

Influence of Microwave on the Structure and NH3-SCR Denitration Activity of Cu-ZSM-5 Catalysts

唐剑骁 1马丽萍 1王冬东 1王倩倩1

作者信息

  • 1. 昆明理工大学环境科学与工程学院,昆明 650500
  • 折叠

摘要

Abstract

Copper-based ZSM-5 zeolite catalysts were prepared using different ways of drying, the microwave drying and the conventional way, that is, electric blasting drying, based on incipient wetness impregnation method.XRD and N2 physisorption techniques were employed to investigate the effect of drying method on porous structure, phase structure as well as catalytic activity.The results show that copper introduction significantly promotes the catalytic activity;below 200 ℃ the catalytic activity of the microwave-dried M-4Cu-ZSM-5 is slightly higher than the conventionally-dried 4Cu-ZSM-5, while between 200-300 ℃ the latter exhibites superior catalytic performance;porous structure, crystal size and distribution of the active species of the catalyst were directly affected by the microwave treatment, causing the differences in catalytic activity.

关键词

SCR/干燥方法/微波/铜基分子筛

Key words

SCR/drying method/microwave/copper-based zeolite

分类

化学化工

引用本文复制引用

唐剑骁,马丽萍,王冬东,王倩倩..微波对Cu-ZSM-5催化剂结构及低温NH3-SCR脱硝活性的影响[J].人工晶体学报,2017,46(8):1569-1574,6.

人工晶体学报

OA北大核心CSCDCSTPCD

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