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高温固相法合成LiNi0.6CO0.2Mn0.2O2的电化学性能

盛锁江 王振伟 耿海龙 徐艳辉

电池2017,Vol.47Issue(4):196-198,3.
电池2017,Vol.47Issue(4):196-198,3.DOI:10.19535/j.1001-1579.2017.04.002

高温固相法合成LiNi0.6CO0.2Mn0.2O2的电化学性能

Electrochemical performance of LiNi0.6Co0.2Mn0.2O2 synthesized via high-temperature solid-state method

盛锁江 1王振伟 2耿海龙 2徐艳辉1

作者信息

  • 1. 苏州大学物理与光电·能源学部,江苏苏州215006
  • 2. 山东齐星新材料科技有限公司,山东邹平256200
  • 折叠

摘要

Abstract

Using LiOH · H2O as the Li-source,LiNi0.6Co0.2Mn0.2O2 cathode was synthesized via high-temperature solid-state method.The influence of the synthesis temperature on the micro-morphology and Li-intercalation behavior of the product was investigated.The phase composition and microstructure were analyzed via XRD and SEM.The crystalline structure was α-NaFeO2type and no impurity was detected.The sample synthesized at 800 ℃ exhibited the best electrochemical performance.In the range of 3.0-4.3 V,the initial discharge capacity was 172 mAh/g,when the discharge current was set up at 28 mA/g.The discharge capacity was 159.4 mAh/g at the 100th cycle.

关键词

锂离子电池/富镍正极材料/嵌脱锂/电化学性能

Key words

Li-ion battery/Ni-rich cathode/lithium intercalation and de-intercalation/electrochemical performance

分类

信息技术与安全科学

引用本文复制引用

盛锁江,王振伟,耿海龙,徐艳辉..高温固相法合成LiNi0.6CO0.2Mn0.2O2的电化学性能[J].电池,2017,47(4):196-198,3.

电池

OA北大核心CSCDCSTPCD

1001-1579

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