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液态Wood合金在氢氧化钠电解质溶液中的电毛细变形现象

张国堤 林巧力 陈剑虹 曹睿

电化学2017,Vol.23Issue(4):429-434,6.
电化学2017,Vol.23Issue(4):429-434,6.DOI:10.13208/j.electrochem.160411

液态Wood合金在氢氧化钠电解质溶液中的电毛细变形现象

Electric Current Induced Flow and Electrocapillary Deformation of Liquid Wood Alloy in NaOH Aqueous Solution

张国堤 1林巧力 1陈剑虹 1曹睿1

作者信息

  • 1. 兰州理工大学,省部共建有色金属先进加工与再利用国家重点实验室,甘肃兰州730050
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摘要

Abstract

The phenomena of the electric current induced flow and electrocapillary deformation for a liquid Wood alloy in a NaOH electrolyte were studied.Electrocapillary behaviors for the liquid Wood alloy in NaOH electrolytes by applying external low voltages were investigated.The electrode reaction (redox reaction) induced the formation or removal of an oxide film,and further caused the drop deformation by decreasing or increasing an interracial tension.The same polar charge in the electric double layer would also decrease the interfacial tension.In order to maintain the stability of system,the contact area of the interface would be expanded,which induces the drop deformation macmscopically.When the liquid metal was charged by the chemical reaction in the solution,the electric field force became an effective way to drive its movement in the electrolyte.

关键词

电毛细作用/铺展动力/表面张力

Key words

capillarity/spreading dynamics/surface tension

分类

化学化工

引用本文复制引用

张国堤,林巧力,陈剑虹,曹睿..液态Wood合金在氢氧化钠电解质溶液中的电毛细变形现象[J].电化学,2017,23(4):429-434,6.

基金项目

国家自然科学基金项目(No.51301083,No.51665031)和甘肃省杰出青年基金项目(No.1506RJDA087)资助 (No.51301083,No.51665031)

电化学

OA北大核心CSCDCSTPCD

1006-3471

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