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铬离子掺杂锰酸锂电池高温溶解性的图像分析

刘利平 尹静涛

电源技术2017,Vol.41Issue(8):1121-1123,3.
电源技术2017,Vol.41Issue(8):1121-1123,3.

铬离子掺杂锰酸锂电池高温溶解性的图像分析

Image analysis of chromium doping on LiMn2O4 spinel high temperature solubility

刘利平 1尹静涛2

作者信息

  • 1. 华北理工大学,河北唐山063000
  • 2. 河北能源职业技术学院,河北唐山063004
  • 折叠

摘要

Abstract

The dissolution behavior of Cr and Mn ions in LiMn2-xCrxO4 under different temperatures was studied by scanning electron microscopy.When the LiMn2-xCrxO)4 powder was immersed in an electrolyte containing LiPF6,the chromium and manganese ions were dissolved.Chromium ion in LiMn2-xCrxO4 was increased.Under the normal temperature and high temperature conditions,the amount of dissolved manganese ions were significantly reduced.This shows that in LiMn2O4 doped chromium ions,the dissolution of manganese ions is inhibited at high temperatures,and therefore a decline in capacity is lead.In addition,the amount of dissolved quantity of chromium ions and manganese ions would be significantly increased with the increasing of the immersion temperature.This shows that temperature plays a key role in the dissolution of Cr doped and non doped LiMn2O4.

关键词

铬离子/锰酸锂电池/高温溶解性能/图像

Key words

chromium ion/LiMn2O4 battery/high temperature solubility/image

分类

信息技术与安全科学

引用本文复制引用

刘利平,尹静涛..铬离子掺杂锰酸锂电池高温溶解性的图像分析[J].电源技术,2017,41(8):1121-1123,3.

基金项目

唐山市科学技术研究与发展计划项目(15130205B) (15130205B)

河北省科技厅重点研发计划自筹项目(15210343) (15210343)

电源技术

OA北大核心CSCDCSTPCD

1002-087X

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