影像科学与光化学2017，Vol.35Issue(5)：667-674,8.DOI:10.7517/j.issn.1674-0475.2017.04.027
微流光反应技术制备树脂状维生素D3
Preparation of Resin-like Vitamin D3 by Micro-flow Photoreaction
李超 1周前雄 1张宝文 1王雪松1
作者信息
- 1. 中国科学院理化技术研究所光化学转换与功能材料重点实验室,北京100190
- 折叠
摘要
Abstract
The key process in the synthesis of vitamin D3 is the photochemical conversion from 7-dehydrocholesterol to pre-vitamin D3,which is currently carried out in batch photoreactors and suffers from low conversion efficiency,recycle of unreacted 7-dehydrocholesterol,and long production period.Using micro-flow photoreactor instead of batch photoreactor,the conversion yield of 7-dehydrocholesterol may be increased from less than 30％ to over 95％,allowing the photoreaction product to be directly used to prepare resin-like vitamin D3 through a thermal isomerization reaction and shortening the production period greatly.关键词
维生素D3/7-去氢胆固醇/预维生素D3/微流光化学反应器Key words
vitamin D3/7-dehydrocholesterol/pre-vitamin D3/micro-flowphotoreactor引用本文复制引用
李超,周前雄,张宝文,王雪松..微流光反应技术制备树脂状维生素D3[J].影像科学与光化学,2017,35(5):667-674,8.
